Structural formation and leaching behavior of mechanically activated lignite fly ash based geopolymer

Geopolymers are inorganic polymers which can be produced by the reaction of aluminium silicate oxides and alkaline silicates in an alkaline medium. Nowadays, silicate bearing wastes, such as fly ash or slag and other by-products of power stations are very common raw materials for geopolymers. In our research a lignite type fly ash was mechanically activated in a high energy density mill (HEM) for different retention time, and geopolymer specimens were produced from these materials. After determining the optimal fly ash fineness, the concentration and composition of the alkaline activator solution were also investigated. The highest compressive strength was reached using fly ash with 2 m2/g specific surface area, activated with a mixture of Na-K silicate (water glass) and NaOH solution. The total dosage of alkaline activators to the fly ash was 40 m/m%, the NaOH activator of 12 M solution represented 25 m/m %, while Na-K silicate 75 m/m%. Then, the leaching properties of the main components and the mobility of toxic elements of the produced geopolymers were tested in distilled water, 1M acetic acid and 1M hydrochloric acid as well. The lowest mobility of the elements was obtained in most cases by the activator containing 100m/m% Na-K silicate solution (water glass) using the mechanically activated fly ash

Riparian buffer strips influence nitrogen losses as nitrous oxide and leached N from upslope permanent pasture

Riparian buffer strips can have a significant role in reducing nitrogen (N) transfers from agricultural land to freshwater primarily via denitrification and plant uptake processes, but an unintended trade-off can be elevated nitrous oxide (N2O) production rates. Against this context, our replicated bounded plot scale study investigated N2O emissions from un-grazed ryegrass pasture served by three types of riparian buffer strips with different vegetation, comprising: (i) grass riparian buffer with novel deep-rooting species, (ii) willow (young trees at establishment phase) riparian buffer, and (iii) deciduous woodland (also young trees at establishment phase) riparian buffer. The experimental control was ryegrass pasture with no buffer strip. N2O emissions were measured at the same time as total oxidized N in run-off, and soil and environmental characteristics in the ri parian buffer strips and upslope pasture between 2018 and 2019. During most of the sampling days, the no-buffer control treatment showed significantly (P < 0.05) greater N2O fluxes and cumulative N2O emissions compared to the remainder of the treatments. Our results also showed that the grass riparian buffer strip is a sink of N2O equivalent to − 2310.2 g N2O-N ha− 1 day− 1 (95% confidence interval:− 535.5 to 492). Event-based water quality results obtained during storms (12 November 2018 and 11 February 2019) showed that the willow riparian buffer treatment had the highest flow-weighted mean N concentrations (N-FWMC) of 0.041 ± 0.022 and 0.031 ± 0.015 mg N L− 1, when compared to the other treatments. Our 9-month experiment therefore, shows that ri parian buffer strips with novel deep-rooting grass can therefore potentially address emissions to both water and air. The results imply that over a shorter timeline similar to the current study, the grass riparian buffer strip can potentially address N emission to both air and water, particularly when serving a permanent pasture in similar settings as the current experiment.Fil: Dlamini, J.C. Crop and Climate Sciences. Departament of Soil; Sudáfrica. Rothamsted Research. Sustainable Agriculture Sciences; Reino Unido. University of Pretoria. Department of Plant and Soil Sciences; SudáfricaFil: Cardenas, L.M. Rothamsted Research. Sustainable Agriculture Sciences; Reino Unido.Fil: Tesfamarian, E.H. University of Pretoria. Department of Plant and Soil Sciences; SudáfricaFil: Dunn, R.M. Rothamsted Research. Sustainable Agriculture Sciences; Reino Unido.Fil: Loick, N. Rothamsted Research. Sustainable Agriculture Sciences; Reino Unido.Fil: Charteris, A.F. Rothamsted Research. Sustainable Agriculture Sciences; Reino Unido.Fil: Cocciaglia, L. Università degli Studi di Perugia. Dipartimento di Scienze Agrarie, Alimentari e Ambientali; ItaliaFil: Vangeli, Sebastián. Instituto Nacional de Tecnología Agropecuaria (INTA). Instituto de Clima y Agua; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Agronomía. Departamento de Ingeniería Agrícola y Uso de la Tierra. Cátedra de Manejo y Conservación de Suelo; ArgentinaFil: Blackwell, M.S.A. Rothamsted Research. Sustainable Agriculture Sciences; Reino Unido.Fil: Upadhayay, H.R. Rothamsted Research. Sustainable Agriculture Sciences; Reino Unido.Fil: Hawkins, J.M.B. Rothamsted Research. Sustainable Agriculture Sciences; Reino Unido.Fil: Evans, J. Rothamsted Research. Computational and Analytical Sciences; Reino UnidoFil: Collins, A.L. Rothamsted Research. Sustainable Agriculture Sciences; Reino Unido

Asymptotic Expansions for Stationary Distributions of Perturbed Semi-Markov Processes

New algorithms for computing of asymptotic expansions for stationary distributions of nonlinearly perturbed semi-Markov processes are presented. The algorithms are based on special techniques of sequential phase space reduction, which can be applied to processes with asymptotically coupled and uncoupled finite phase spaces.Comment: 83 page

17-OHPC to Prevent Recurrent Preterm Birth in Singleton Gestations (PROLONG Study): A Multicenter, International, Randomized Double-Blind Trial

Background âwomen with a history of spontaneous preterm birth (SPTB) are at a significantly increased risk for recurrent preterm birth (PTB). To date, only one large U.S. clinical trial comparing 17-OHPC (17-α-hydroxyprogesterone caproate or 17P) to placebo has been published, and this trial was stopped early due to a large treatment benefit. Objective âThis study aimed to assess whether 17-OHPC decreases recurrent PTB and neonatal morbidity in women with a prior SPTB in a singleton gestation. Study Design âThis was a double-blind, placebo-controlled international trial involving women with a previous singleton SPTB (clinicaltrials.gov: NCT 01004029). Women were enrolled at 93 clinical centers (41 in the United States and 52 outside the United States) between 16 0/7 to 20 6/7 weeks in a 2:1 ratio, to receive either weekly intramuscular (IM) injections of 250 mg of 17-OHPC or an inert oil placebo; treatment was continued until delivery or 36 weeks. Co-primary outcomes were PTB &lt; 35 weeks and a neonatal morbidity composite index. The composite included any of the following: Neonatal death, grade 3 or 4 intraventricular hemorrhage, respiratory distress syndrome, bronchopulmonary dysplasia, necrotizing enterocolitis, or proven sepsis. A planned sample size of 1,707 patients was estimated to provide 98% power to detect a 30% reduction in PTB &lt; 35 weeks (30% to 21%) and 90% power to detect a 35% reduction in neonatal composite index (17%-11%) using a two-sided type-I error of 5%. Finally, this sample size would also provide 82.8% power to rule out a doubling in the risk of fetal/early infant death assuming a 4% fetal/early infant death rate. Analysis was performed according to the intention-to-treat principle. Results âaseline characteristics between the 1,130 women who received 17-OHPC and 578 women who received placebo were similar. Overall, 87% of enrolled women were Caucasian, 12% had &gt;1 prior SPTB, 7% smoked cigarettes, and 89% were married/lived with partner. Prior to receiving study drug, 73% women had a transvaginal cervical length measurement performed and &lt;2% had cervical shortening &lt;25 mm. There were no significant differences in the frequency of PTB &lt; 35 weeks (17-OHPC 11.0% vs. placebo 11.5%; relative risk = 0.95 [95% confidence interval (CI): 0.71-1.26]) or neonatal morbidity index (17-OHPC 5.6% vs. placebo 5.0%; relative risk = 1.12 [95% CI: 0.68-1.61]). There were also no differences in frequency of fetal/early infant death (17-OHPC 1.7% vs. placebo 1.9%; relative risk = 0.87 [95% CI: 0.4-1.81]. Maternal outcomes were also similar. In the subgroup of women enrolled in the United States (n = 391; 23% of all patients), although the rate of PTB &lt; 35 weeks was higher than the overall study population, there were no statistically significant differences between groups (15.6% vs. 17.6%; relative risk = 0.88 [95% CI: 0.55, 1.40]. Conclusion âin this study population, 17-OHPC did not decrease recurrent PTB and was not associated with increased fetal/early infant death

Cognitive dimensions questionnaire applied to exploratory algorithm design

In software engineering, the stage between problem realization and implementation of a solution is not well supported by technology. It is common to see work being carried out on paper or whiteboards. This paper documents a pilot study to identify some reasons as to why paper and whiteboards are useful tools in early exploratory design and exposes some questions about where technology may fit in augmenting this stage of software engineering. The cognitive dimensions questionnaire was used to investigate notations and devices used in exploratory algorithm design